$C{H}_{3}COOH+NaOH\to C{H}_{3}COONa+H_{2}O$

$\Rightarrow n_{C{H}_{3}COOH}=n_{NaOH}=0,05.2=0,1mol$

$m_{C{H}_{3}COOH}=0,1.60=6g$

$\Rightarrow \%m_{C{H}_{3}COOH}=\frac{6.100}{12,9}=46,5\%$

$\%m_{C_2{H}_{5}OH}=100-46,5=53,5\%$ 

b,

\(n_{NaOH}=0,4.0,5=0,2\left(mol\right)\)

PT: \(CH_3COOH+NaOH\rightarrow CH_3COONa+H_2O\)

Theo PT: \(n_{CH_3COOH}=n_{NaOH}=0,2\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{CH_3COOH}=\dfrac{0,2.60}{15,2}.100\%\approx78,95\%\\\%m_{C_2H_5OH}\approx21,05\%\end{matrix}\right.\)

a, Gọi \(\left\{{}\begin{matrix}n_{C_2H_5OH}=a\left(mol\right)\\n_{CH_3COOH}=b\left(mol\right)\end{matrix}\right.\)

\(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)

PTHH: 

2C₂H₅OH + 2Na ---> 2C₂H₅ONa + H₂

a---------------------------------------->0,5a

2CH₃COOH + 2Na ---> 2CH₃COONa + H₂

b------------------------------------------------>0,5b

=> hệ pt \(\left\{{}\begin{matrix}46a+60b=48,8\\0,5a+0,5b=0,5\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,8\left(mol\right)\\b=0,2\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{C_2H_5OH}=0,8.46=36,8\left(g\right)\\m_{CH_3COOH}=0,2.60=12\left(g\right)\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}\%m_{C_2H_5OH}=\dfrac{36,8}{48,8}.100\%=75,41\%\\\%m_{CH_3COOH}=100\%-75,41\%=24,59\%\end{matrix}\right.\)

b, PTHH:

\(C_2H_5OH+CH_3COOH\xrightarrow[t^o]{H_2SO_4đặc}CH_3COOC_2H_5+H_2O\)

LTL: 0,8 > 0,2 => Rượu dư

\(n_{CH_3COOC_2H_5\left(tt\right)}=0,2.85\%=0,17\left(mol\right)\\ m_{este}=0,17.88=14,96\left(g\right)\)

a.Gọi \(\left\{{}\begin{matrix}n_{C_2H_5OH}=x\\n_{CH_3COOH}=y\end{matrix}\right.\)

\(n_{H_2}=\dfrac{11,2}{22,4}=0,5mol\)

\(2C_2H_5OH+2Na\rightarrow2C_2H_5ONa+H_2\)

             x                                          1/2 x         ( mol )

\(2CH_3COOH+Na\rightarrow2CH_3COONa+H_2\)

        y                                                      1/2 y       ( mol )

Ta có:

\(\left\{{}\begin{matrix}46x+60y=48,8\\\dfrac{1}{2}x+\dfrac{1}{2}y=0,5\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,8\\y=0,2\end{matrix}\right.\)

\(\rightarrow m_{C_2H_5OH}=0,8.46=36,8g\)

\(\rightarrow\left\{{}\begin{matrix}\%m_{C_2H_5OH}=\dfrac{36,8}{48,8}.100=75,4\%\\\%m_{CH_3COOH}=100\%-75,4\%=24,6\%\end{matrix}\right.\)

b.\(C_2H_5OH+CH_3COOH\rightarrow\left(H_2SO_4\left(đ\right),t^o\right)CH_3COOC_2H_5+H_2O\)

        0,8     <          0,2                                                                       ( mol )

                               0,2                                             0,2                    ( mol )

\(m_{CH_3COOC_2H_5}=0,2.88.85\%=14,96g\) 

Đáp án : C

Ta có: 

60nCH3COOH + 72nC2H3COOH + 74nC2H5COOH=3,15

nC2H3COOH=nBr2=0,02

nCH3COOH + nC2H3COOH + nC2H5COOH=nNaOH=0,045

=> nCH3COOH = 0,01 mol

=> % CH3COOH =  0 , 01 . 60 3 , 15  = 19,05 %

\(a,n_{NaOH}=1,5.0,2=0,3\left(mol\right)\\ n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)

PTHH: 

CH₃COOH + NaOH ---> CH₃COONa + H₂O

0,3<-----------0,3

2CH₃COOH + 2Na ---> 2CH₃COONa + H₂

0,3----------------------------------------------->0,15

2C₂H₅OH + 2Na ---> 2C₂H₅ONa + H₂

0,2<---------------------------------------0,1

=> m = 0,2.46  +0,3.60 = 27,2 (g)

b) \(\left\{{}\begin{matrix}\%m_{CH_3COOH}=\dfrac{0,3.60}{27,2}.100\%=66,18\%\\\%m_{C_2H_5OH}=100\%-66,18\%=33,82\%\end{matrix}\right.\)

a) Gọi số mol CH₃COOH, C₂H₅OH là a, b (mol)

=> 60a + 46b = 25,8 (1)

\(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)

PTHH: 2Na + 2CH₃COOH --> 2CH₃COONa + H₂

                               a------------------------->0,5a

           2Na + 2C₂H₅OH --> 2C₂H₅ONa + H₂

                           b--------------------->0,5b

=> 0,5a + 0,5b = 0,25 (2)

(1)(2) => a = 0,2 (mol); b = 0,3 (mol)

=> \(\left\{{}\begin{matrix}\%m_{CH_3COOH}=\dfrac{0,2.60}{25,8}.100\%=46,51\%\\\%m_{C_2H_5OH}=\dfrac{0,3.46}{25,8}.100\%=53,49\%\end{matrix}\right.\)

b) 

\(n_{CH_3COOC_2H_5}=\dfrac{13,2}{88}=0,15\left(mol\right)\)

PTHH: CH₃COOH + C₂H₅OH --H₂SO_4(đ),t^o--> CH₃COOC₂H₅ + H₂O

Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,3}{1}\) => Hiệu suất tính theo CH₃COOH

PTHH: CH₃COOH + C₂H₅OH --H₂SO_4(đ),t^o--> CH₃COOC₂H₅ + H₂O

                   0,15<---------------------------------0,15

=> \(H=\dfrac{0,15}{0,2}.100\%=75\%\)

Đáp án C

Đặt số mol 3 axit lần lượt là a b và c ta có:

60a + 74b + 72c = 6,3 gam (PT theo khối lượng hỗn hợp). (1)

c = 6,4:160 = 0,04 mol (PT theo số mol brom phản ứng). (2)

Để pứ hoàn toàn với 3,15 gam X cần 0,045 mol NaOH ⇒ 6,3 gam X cần 0,09 mol NaOH.

⇒ a + b + c = 0,09 (PT theo số mol NaOH pứ) (3).

+ Giải hệ (1) (2) và (3) ⇒ a = n_{Axit axetic} = a = 0,02 mol ⇒ m_{Axit axetic} = 1,2 gam.

⇒ %m_{Axit axetic/hh} =  1 , 2 × 100 6 , 3  ≈ 19,05% 

Đáp án A